CBSE · Class 11 · Chemistry · Chapter 5

Chemical Thermodynamics

Energy changes, enthalpy and thermodynamics.

10 lessons 170 min
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Lessons in this chapter

  1. 1Systems, States, and the First LawLearn to define a thermodynamic system and account for the energy it receives or gives out.
  2. 2Pressure–Volume Work and Gas ExpansionUse pistons and pressure–volume graphs to understand how the route of expansion controls work.
  3. 3Enthalpy, Heat Capacity, and CalorimetryConnect measurable temperature changes with internal energy and enthalpy.
  4. 4Reaction Enthalpy, Standard States, and Phase ChangesInterpret reaction heat using specified states, then follow energy through melting, evaporation, cooling, and freezing.
  5. 5Formation Enthalpies and Hess’s LawCalculate otherwise inaccessible reaction heats by combining consistent reference data and reaction paths.
  6. 6Combustion, Atomisation, and Bond EnthalpyConnect fuel energy with the energy required to separate atoms and break chemical bonds.
  7. 7Lattice, Solution, and Dilution EnthalpiesUse energy cycles to explain how ionic crystals form, dissolve, and respond to added solvent.
  8. 8Spontaneity, Entropy, and the Thermodynamic LawsExplain the preferred direction of change using the entropy of both system and surroundings.
  9. 9Gibbs Energy, Temperature, and EquilibriumUse enthalpy and entropy together to predict direction and relate standard free energy to equilibrium.
  10. 10Chapter Summary and PracticeConnect energy accounting, reaction-energy cycles, entropy, and equilibrium in a complete thermodynamics review.